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Journal Articles

A Novel method to improve methane generation from waste sludge using iron nanoparticles coated with magnesium hydroxide

Eljamal, R.*; Maamoun, I.; Bensaida, K.*; Yilmaz, G.*; Sugihara, Yuji*; Eljamal, O.*

Renewable and Sustainable Energy Reviews, 158, p.112192_1 - 112192_13, 2022/04

 Times Cited Count:25 Percentile:95.43(Green & Sustainable Science & Technology)

JAEA Reports

Safe, efficient cementation of challenging radioactive wastes using alkali activated materials with high-flowability and high-anion retention capacity (Contract research); FY2020 Nuclear Energy Science & Technology and Human Resource Development Project

Collaborative Laboratories for Advanced Decommissioning Science; Hokkaido University*

JAEA-Review 2021-036, 95 Pages, 2021/12

JAEA-Review-2021-036.pdf:5.13MB

The Collaborative Laboratories for Advanced Decommissioning Science (CLADS), Japan Atomic Energy Agency (JAEA), had been conducting the Nuclear Energy Science & Technology and Human Resource Development Project (hereafter referred to "the Project") in FY2020. The Project aims to contribute to solving problems in the nuclear energy field represented by the decommissioning of the Fukushima Daiichi Nuclear Power Station, Tokyo Electric Power Company Holdings, Inc. (TEPCO). For this purpose, intelligence was collected from all over the world, and basic research and human resource development were promoted by closely integrating/collaborating knowledge and experiences in various fields beyond the barrier of conventional organizations and research fields. The sponsor of the Project was moved from the Ministry of Education, Culture, Sports, Science and Technology to JAEA since the newly adopted proposals in FY2018. On this occasion, JAEA constructed a new research system where JAEA-academia collaboration is reinforced and medium-to-long term research/development and human resource development contributing to the decommissioning are stably and consecutively implemented. Among the adopted proposals in FY2019, this report summarizes the research results of the "Safe, efficient cementation of challenging radioactive wastes using alkali activated materials with high-flowability and high-anion retention capacity" conducted in FY2020. For safe storage and disposal of iron sludge generated from contaminated water treatment, the present study aims to 1) explore alkali activated materials (AAM) with high-flowability and high-anion retention capacity and its recipe, 2) try mock-up manufacture and evaluation for one-tenth the size of real waste and propose the concept of the manufacturing equipment for a real plant, 3) show potential of AAM as the material for the solidification of waste with various physicochemical properties and radioactive nuclide compositions from the result ...

Oral presentation

Composition optimization of iron phosphate glasses for radioactive sludge

Takebe, Hiromichi*; Kitamura, Naoto*; Amamoto, Ippei; Kobayashi, Hidekazu; Mitamura, Naoki*; Tsuzuki, Tatsuya*

no journal, , 

The great amount of water used for cooling the stricken power reactors at Fukushima Dai-ichi following the earthquake and tsunami on March 11, 2011 has resulted in the accumulation of the remaining water. The water is subsequently contaminated by fission products and some other radioactive substances. The initial treatment to remove the radioactive substances from the cooling water again produced a secondary radioactive waste, the sludge. Iron phosphate glass powder/frit and main component of raw materials for simulated sludge, e.g., barium sulfate and potassium nickel ferrocyanide with various concentrations, were mixed for melting batch. The temperature required for the formation of homogeneous melt was determined by the direct observation of sample decomposition and melting processes on the thermocouple filament through a microscope. The mixtures for bulk glasses were melted in air using platinum crucibles. The quenched glass samples consisted mainly of oxide constituents due to the decomposition of the sludge components during heating and melting processes. Characteristic temperatures of glass transition, Tg, and onset of crystallization, Tx, was determined by differential thermal analysis. Thermal stability against crystallization for the glass samples was evaluated by the temperature difference between Tx and Tg. Water durability was determined by the weight change per a specific surface area after immersion test in hot water at 120$$^{circ}$$C for 72 hours based on MCC-2 static leaching method. Phosphate network species and chemical bonding were characterized by Raman spectroscopy. Glass composition melted with the stimulated sludge components is optimized in terms of both thermal stability and water durability with the characterization of O/P molar ratio.

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